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discharge, but also in large measure to an alternate process of exhaustion and restoration of excitability on the part of the responding tissues-the ganglionic period coinciding with that during which the process of restoration lasts, and the ganglionic discharge being thus always thrown in at the moment when the excitability of the responding tissues is at its climax.

Light has been found to stimulate the lithocysts of covered-eyed Medusæ into increased activity, thus proving that these organs, like the marginal bodies of the naked-eyed Medusa, are rudimentary organs of vision.

The polypite of Aurelia aurita has been proved to execute movements of localization of stimuli, somewhat similar to those which the author has already described as being performed by the polypite of Tiaropsis indicans.

Alternating the direction of the constant current in the muscular tissues of the Medusæ has the effect of maintaining the make and break stimulations at their maximum value; but the value of these stimulations rapidly declines if they are successively repeated with the current passing in the same direction.

In the sub-umbrella of the Medusa waves of nervous excitation are sometimes able to pass when waves of muscular contraction have become blocked by the severity of overlapping sections.

Exhaustion of the sub-umbrella tissues-especially in narrow connecting isthmuses of tissue-may have the effect of blocking the passage of contractile waves.

Lithocysts have been proved sometimes to exert their ganglionic influence at comparatively great distances from their own seats-contractile waves, originating at points in the sub-umbrella tissue remote from a lithocyst, and ceasing to originate at that point when the lithocyst is removed. A nervous connexion of this kind may be maintained between a lithocyst and the point at which the waves of contraction originate even after severe forms of section have been interposed between the lithocyst and that point.

When the sub-umbrella tissue of Aurelia is cut throughout its whole diameter, the incision will again heal up, sufficiently to restore physiological continuity, in from four to eight hours.

January 23, 1879.

W. SPOTTISWOODE, M.A., D.C.L., President, in the Chair.

The Presents received were laid on the table, and thanks ordered for them.

The following Papers were read :

I. “Researches on Chemical Equivalence. Part I. Sodic and

Potassic Sulphates." By EDMUND J. Mills, D.Sc., F.R.S. “Young” Professor of Technical Chemistry in Anderson's College, Glasgow, and T. U. WALTON, B.Sc. Received

October 16, 1878. The conception of a chemical equivalent as employed in these researches corresponds to a definition first given* by one of us, viz., that the chemical equivalent of a body is that weight of it which does the unit of work. We do not therefore use the term in its ordinary sense; as, for example, when it is said that H is "equivalent” to CI, Na, &c.

The following experiments were arranged with the view of determining the effect of potassic and sodic sulphates on the rate of formation of ammonia, when nascent hydrogen is made to act on potassic nitrate. Judging from their behaviour in other cases, it was expected that in this instance, also, their action would be one of retardation. Experi. ment, however, has proved the reverse, on the whole, to be true.

The extremely delicate nature of the reaction, which is liable to be spoiled by the accidental falling in of a single speck of dust, or by slight variation of temperature, or unequal exposure of the different solutions to light, rendered the attempt to measure the effect a matter of peculiar difficulty.

At first, common sheet zinc, thoroughly cleansed from grease, was placed in a solution of potassic nitrate and hydrate, and the amount of ammonia formed during periods varying from twenty-four hours to one week was measured. But the results were very irregular and unsatisfactory. Galvanic couples seemed to be established at certain points on the surface of the zinc, probably due to the presence of iron or lead as impurities. Thin zinc foil was next tried, but with little better result; neither were any alterations in the shape or disposition of the foil attended with success. Fresh experiments were also nndertaken with sodium amalgam instead of zinc and potassic nitrate; but the action, though rather more uniform, was still very uncertain. It was found impossible to obtain a perfectly homogeneous solution of sodium in mercury, entirely free from sodic oxide and hydrate; and this seriously impaired the accuracy of measuring out the amalgam.

The only plan which was found to give results at all comparable with each other, was using zinc amalgam and potassic nitrate. The experiments were performed in wide-mouthed glass-stoppered bottles of cylindrical shape, having an internal diameter of 60 mm., and a total capacity of 315 cab. centims. Each bottle contained 1 grm.

• "Philosophical Magazine," [5], i, 14.

potassic

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nitrate, 1 grm. potassic hydrate (prepared from the sulphate

waterand 150 cub. centims. of distilled water, very free from ammonia. The reagents had been carefully purified. 30 cub. centims. of amalgam, prepared by dissolving 10 grms. zinc in 10 kilogs. mercury, were then added, and the "system" was preserved from dust and light. After twenty hours, the amount of ammonia was estimated by Nessler's method. Traces of this substance were occasionally present in the solutions employed, and a corresponding correction had to be made. In every experiment, nine solutions were prepared at the same time—three free from sulphate, three containing sodic sulphate, and three potassic salphate; and the mean of each three was taken as the true value for that particular experiment. Fifteen comparisons of each of nine solutions, arranged in this way, were made with different quantities of sulphate. The temperature was taken at the beginning, in the middle, and at the conclusion of the experiment; the temperature at night being registered by one of the automatic thermometers sold by Negretti and Zambra. Owing to the extreme delicacy of the reaction and the slight causes which suffice to interfere with it, the numbers obtained from single experiments are not sufficiently reliable to measure the precise amount of change caused by varying the quantity of alkaline sulphate. Every comparison, however, though made with a different weight of sulphate from that employed in the others, involved equal weights of potassic and of sodic sulphate; and hence the relative effect of those two bodies has been very clearly approximated to

The following table gives a summary of the observations made :

Ratio.

Grm. sulphate added.

Mean temp. C.

Grm. ammonia

formed in the
blank (150 c.c.). Blank.

Experiment Experiment
with sodic with potassic
salt.

salt.

0:1 *0:1 0.2 0.3 0.3 0.4 *0.5 *0.5 0.6 0.6 0.7 0.8 0.9 *1.0 1.0

18.4
14.6
13 4
16:4
14:1
15.6
15.6
16.3
184
22.6
17:1
15.2
15.4
12.3
17.0

0.0000432
0.0000135
0.0000424
0.0000459
0.0001200
0.0001350
0.0000655
0.0000493
0.0000391
0.0000445
0.0000431
0.0000670
0.0000679
0.0000359
0.0000456

100
100
100
100
100
100
100
100
100
100
100
100
100
100
100

102.2

991 100:1

79.3 103.9 105.4 108.5 110:1

99.5 109.7 104.8 113.8 107 1 111:1 121 7

99.5 88.8 103.2

795 102 0 109.5 97.7 96.6 105 :1 107.8 104.8 113.2 113.4 129.8 114.9

The ratio of the working effect of sodic to that of potassic sulphate, as calculated from the numbers given above, is 100:16 : 100, with a probable uncertainty of 1.3 per cent. This is the mean value, reckoned by the method of least squares, from the whole of the observations. The rejection of the four experiments marked with an asterisk, which differ somewhat widely from the rest, would give the ratio 99:53 : 100, with a probable uncertainty of 0.73 per cent. ; while the probable error of a single observation would then be reduced from 5:02 to 2:4 per cent. [Owing to the number of determinations made, any error in the result is but very slightly affected by error in the ammonia estimation.]

The conclusions which we think may fairly be drawn from these numbers are:(1.) That sodic and potassic sulphates have a well-marked influence

on the reaction to which we have referred; (2.) That as more sulphate is added, the reaction is accelerated ; (3.) That equal weights of sodic and potassic sulphates have as

nearly as possible the same working effect. The last conclusion may be otherwise expressed thus :

If we represent our equivalent of potassic sulphate by a number, then the equivalent of sodic sulphate is represented by the same number.

II. “Researches on Chemical Equivalence.” Part II. Hydric

Chloride and Sulphate. By EDMUND J. MILLS, D.Sc.,
F.R.S., and JAMES HOGARTH. Received December 4, 1878.

While carrying out our researches on lactin,* it struck us that use might be made of it to compare the dynamical equivalents of acid bodies. We accordingly selected hydric chloride and hydric sulphate for the measurements in question, and prepared solutions of these acids, containing respectively 73 grammes hydric chloride (2HCI), and 196 grammes hydric sulphate (2H_SO.) per litre. An experiment was first tried with 5 grammes lactin and 10 cub. centims. of the hydric chloride solution in a total volume of 70 cub. centims. At a temperature of 17° C. there was no change of rotation in twenty. four hours. In a second experiment a similar solution was raised for an hour to 40° C., and then for an hour to 60° C.; but without effect on the rotatory power.

The temperature of 100° C. was finally adopted, the change at that point taking place at a rate admitting of accurate measurement. The method of experiment was as follows: A measuring flask was made marked to contain 60 cub. centims.; in this were placed 50 cub. centims. of a 10 per cent. solution of lactin (i.e., 5 grammes), the acid measured in, and the volume made up to

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the mark. To prevent evaporation during heating, the neck of the flask was left long, and a narrow bent tube attached by an indiarubber joint.

The time was accurately noted when the flask was placed in the bath. After half an hour, the flask was taken out quickly, plunged into cold water, and the contents when cold transferred to the polarimeter tube. The tube used in the researches on lactin had to be modified in these experiments, the cement not being able to withstand the action of the acid. In its altered form, the plate glass covers were secured by two screw rods and nuts, a thin washer of gutta-percha tissue being placed between the ends of the tube and the plates. This washer did not materially affect the length of the column, and made the tube perfectly tight. The length of the tube was thus reduced to 216 millims.

The results of these experiments are given in the following table. The quantity of acid is the only varied condition of experiment..

Action of Hydric Chloride and Hydric Sulphate on Lactin. Total volume in each case 60 cub. centims. Weight of Lactin

=5 grammes.

[blocks in formation]

Half. hour

No. 1. No. 2. No. 3. No. 4. No. 5. No. 6. No. 7. intervals.

4 cub. 4 cub. 17.5 cub. 8 cub. 4 cub. 4 cub. 17.5 cub. centims. centims. centims. centims. centims. centims. centims.

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The equation A is deduced from the average of Nos. 1 and 2 by the method of least squares, the probable error of a single comparison of calculated and experimental numbers being ·0653.

The equation B is similarly deduced from Nos. 5 and 6, its probable error being .0587.

C is the equation to No. 3 with a probable error :0818
D

No. 7

is

•1063 No. 4

•0848

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